Study of thermal stability for tertiary pyridine ion exchange resin and anti-corrosion property of structural material toward eluents used in the advanced ORIENT cycle process

Koyama, Shinichi; Ozawa, Masaki; Kurosawa, Kiyoko*; Tatenuma, Katsuyoshi*; Sato, Yoshihiko*; Okada, Ken*

Journal of Radioanalytical and Nuclear Chemistry, 286(3), p.807 - 813, 2010/12

https://doi.org/10.1007/s10967-010-0745-8

A multi-functional separation process is proposed on the Adv.-ORIENT cycle concept. In this process, hydrochloric acid, mixture of nitric acid and methanol should be used as eluents. Two important subjects should be solved so as to prove the availability. One is corrosion aspect for the use of HCl solution, Tantalum was anti-corrosive in HCl media, and Hastelloy-B seemed to be acceptable at RT, with evidence of low corrosion rate ( 0.1 mm/y). The other is explication of the reactive safety between ion exchange resin and solvent (nitric acid and methanol). The reaction occurred regardless of nitric acid concentration and presence or absence of methanol when the temperature of heater reached 220 C. However, it was confirmed that the reaction did not occur when the heating temperature decreased.